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Overall, this work validated potential applications of Ag-doped NiFe2O4 catalyzed ozonation procedure for biologically recalcitrant wastewater.Molecular level characterization of mixed organic sulfur (DOS) by electrospray ionization-Fourier transform ion cyclotron resonance size spectrometry (ESI-FTICR MS) is essential for further understanding of the role of DOS in the environment. Right here, ESI spray solvent, a key parameter for ion manufacturing during ESI process, had been