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The electroreduction of carbon dioxide to hydrocarbons has been proposed as a promising way to utilize CO2 and maintain the ecosystem carbon balance. However, the selective reduction of CO2 to C2 hydrocarbons is still challenging. In this study, a highly efficient heterostructured catalyst has been developed, composed of a carbon nitride (CN)-encapsulated copper oxide hybrid (Cux O/CN). The interaction between the metal and carbon nitride in the heterostructured catalysts improves the intrinsic electrical conductivity and the charge trans