https://www.selleckchem.com/pr....oducts/apocynin-acet
It is found that both N2 and NNH species have the strongest interaction with M11 leading to the initial activation of N2 on the M11 surface being a spontaneous process. A kinetic model based on the Marcus theory is applied to calculate the potential-dependent reaction barrier of electrochemical hydrogenation steps of the N2 reduction reaction. The rate-determining step is the fifth hydrogenation step *NH → *NH2 on Fe(11 and M11 surfaces, and the first hydrogenation step *N2 → *NNH on Rh(111) and Ru(0001) su
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