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Local microstate control is achieved here via topological magnetic writing using a magnetic force microscope tip.Highly toxic chlorine gas imposes serious health risks in the workplace. The ability to on-site, real-time monitoring of instantaneous and time-weighted average (TWA) chlorine gas concentrations in a simple, sensitive, accurate, and reliable manner would be highly beneficial to improve workplace health and safety. Here, we propose and experimentally validate a gaseous chlorine detection principle based on a N,N-diethyl-p-phenyl