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This is the first report on the construction of a Gastrodin/PU porous film, and the results reveal its promise as a scaffold material for neural tissue engineering. This article is protected by copyright. All rights reserved. This article is protected by copyright. All rights reserved.Metal-organic frameworks (MOFs) have limited applications in electrochemical fields due to their poor conductivity. In this work, an electroactive MOF (E-MOF) is designed as a highly crystallized electrochemiluminescence (ECL) emitter in aqueous medium for the first time. The