https://www.selleckchem.com/products/fsen1.html
Tetravalent cerium alkoxide complexes supported by the Kläui tripodal ligand [Cη5-C5H5)P(O)(OEt)23]- (LOEt-) have been synthesized, and their nucleophilic and redox reactivity have been studied. Treatment of the Ce(IV) oxo complex [CeIV(LOEt)2(O)(H2O)]·MeCONH2 (1) with i PrOH or reaction of [CeIV(LOEt)2Cl2] (2) with Ag2O in i PrOH afforded the Ce(IV) dialkoxide complex [CeIV(LOEt)2(O i Pr)2] (3- i Pr). The methoxide and ethoxide analogues [CeIV(LOEt)2(OR)2] (R = Me (3-Me), Et (3-Et)) have been prepared similarly from 2 and Ag2O in ROH.
Like
Comment
Share
