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Herein we report the development of deacylative thiolation of diverse methyl ketones. The reaction is redox-neutral, and heavy-metal-free, which gives an alternative way to present thioether teams site-specifically to unactivated aliphatic jobs. It features exceptional practical group threshold and broad substrate scope, therefore enabling late-stage derivatization. The process advantages of efficient condensation amongst the activation reagent and ketone substrates,
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