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MCM-22, MCM-36, and ITQ-2 zeolites with the desired Si/Al molar ratios of 15, 25, and 50 were synthetized and tested as catalysts for dehydration of methanol to dimethyl ether and dehydration of ethanol to diethyl ether and ethylene. The outer lining concentration of acid sites was managed because of the synthesis of zeolite precursors with various aluminum content within the zeolite framework, as the impact of porous construction on the overall performance of alc