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The Most Effective ADHD Medication For Adults Adults with ADHD are usually prescribed stimulants. They regulate the levels of two chemical messages within the brain that regulate the attention. The most effective adhd medication for adults is Strattera (atomoxetine). It is available as capsules that can be taken with food or without food. It is effective for a majority of people. It lasts longer than stimulants with less time to take effect like amphetamine and methylphenidate.