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3D monolithic reactor has shown great promise for varied heterogeneous catalysis reactions including water treatment, energy generation and storage, and clean fuel production. As a natural porous material, macroporous wood is regarded as an excellent support for inorganic catalyst due to its abundant polar functional groups and channels. On the other hand, a metal organic framework (MOF) has been widely used as heterogeneous catalyst due to its high specific surface area and large amount of microporosities. Combining macroporous wood an