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Toward the need for solid-state fluorescent quantum dots, resistant to self-quenching, we describe a solvothermal-assisted sol-gel method to synthesize Se quantum dots. Morphological and crystalline characterizations reveal that Se quantum dots (average size 3-8 nm) have a trigonal crystal structure. The presence of planar defects (dislocations, stacking faults, twins, and grain boundaries) suggests formation of Se nanocrystallites through aggregation-based crystal growth mechanisms. Under ultraviolet excitation, the quantum dots exhibi