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This paper investigates the impact of the technological process (Mechanochemical Activation (MA) of the powder in combination with the Spark Plasma Sintering (SPS) method) on the final properties of lead-free Ba(Fe1/2Nb1/2)O3 (BFN) ceramic materials. The BFN powders were obtained for different MA duration times (x from 10 to 100 h). The mechanically activated BFN powders were used in the technological process of the BFN ceramics by the SPS method. The measurements of the BFNxMA ceramic samples included the following analysis Scanning Elect