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Large and significant differences in chemical composition of peat and the properties of HAs were found to be related to the degree of decomposition. The HAs from drained peatlands were less chemically mature. In contrast, the HAs from fen and raised bog were found to be more mature than that of the corresponding drained peatlands. The above findings showed the distinguishable structure of HAs within the soil profile created by the plant residue biodegradation and formed in both oxic and anoxic conditions. The analytical methods of thermal