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Based on previous reports, UV/sulfite process is generally used as an advanced reduction process (ARP) since eaq- and/or ∙H, both with strong reduction potential, could be substantially generated herein. Very recently, the combination of UV and sulfite as an advanced oxidation process (AOP) or an oxidation-reduction coupling process has attracted increasing interest due to the yield of SO4∙- and/or HO∙. Herein, the application of UV/sulfite as an ARP and AOP (or oxidation-reduction coupling process) during water and wastewater treatment