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The crystallization of S°, barite and calcite and the good correlations between Ba, Sr and Ca indicated that previously precipitated sulfide can be oxidized by the activity of a relevant sulfur-oxidizing bacterial community (Thioalkalimicrobium, Sulfurovum, Arcobacter and Sulfurimonas), possibly facilitating the release of the metals.Namaqualand, South Africa, is a global biodiversity hotspot but local populations are affected by challenging economic conditions largely because of poor access to water. In this study groundwater types are