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It was found that larger vesicles were formed from smaller precursor particles and that monodisperse precursors are required for formation of very monodisperse vesicles upon temperature increase. At high glycyrrhizin contents and above a critical heating rate of ∼5°C min-1, the polydispersity of these vesicles is decoupled from both parameters, glycyrrhizin content and heating rate. However, the vesicle size stays tunable by the glycyrrhizin content and increases upon increasing the glycyrrhizin concentration. Therefore, vesicles of defin
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