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It is well known that using chlorine dioxide (ClO2) as a disinfectant inevitably produces a common disinfection byproducts chlorite (ClO2‒). In this study, we found that UV photolysis after ClO2 disinfection can effectively eliminate both ClO2‒ and contaminants of emerging concern (CECs). However, the kinetic mechanisms of UV/ClO2‒ process destructing CECs, as well as transformation of ClO2‒ in UV/ClO2‒ system are not clear yet. Therefore, we systematically investigated the UV/ClO2‒ system to assist us appropriately design this process un