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The Au NF@Pd arrays display 4.1 times higher specific activity and 13.7 times higher mass activity than the commercial Pd/C electrocatalyst. Moreover, the nanostructure shows improved stability towards the ethanol oxidation reaction. This study enriches the manufacturing technology to increase the active sites of noble metal nanocatalysts and promotes the development of direct ethanol fuel cells.A series of tris(trimethylsilylmethyl) yttrium donor adduct complexes was synthesized and fully characterized by X-ray diffraction, 1H/13C/29S