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Particularly, the IL@MIL-101 (SIB-3) unfolds a high proton conductivity (σ = 4.4 × 10-2 S cm-1) at RH only ~23%, five orders of magnitude boost than compared to parent MIL-101 (1.1 × 10-7 S cm-1) at 323 K. Besides, IL@MIL-101s as fillers are integrated into polymer blends to form hybrid membranes, appearing the relatively high proton conductivity (4.3 × 10-3 S cm-1) under ~23% RH at 323 K. HYPOTHESIS Liquid drainage through foams is a multiscale pro