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The results show that the δ-Al2O3 phase contains three distinct AlO sites and three distinct AlT sites. This detailed Al site structural information offers a powerful way of analyzing the most complex γ-Al2O3 spectrum. It is found that the γ-Al2O3 phase consists of Al sites with local structures similar to those found in the δ-Al2O3 and θ-Al2O3 phases albeit with less ordering. Spin-lattice relaxation time measurement further confirms the disordering of the lattice. Collectively, this study uniquely assigns 27Al features in transition alu