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Investigating a molecular heterodimer as an example, we demonstrate the utility of anisotropy in EEI2D spectroscopy for disentangling dynamic localization and annihilation. We further calculate the annihilation in extended systems such as conjugated polymers. In a polymer, a change in the anisotropy provides a unique signature for exciton transport between differently oriented sections. We analyze three types of geometry variations in polymers a kink, varying geometric and energetic disorder, and different geometric domains. Our findings