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A facile strategy to elevate gas separation performances of polymers is to introduce a versatile particle. In this study, the novel F-Ce nanosheets are synthesized, and then F-Ce is functionalized with 1-ethyl-3-methylimidazole thiocyanate (ionic liquids, ILs), obtaining multifunctional f-F-Ce nanosheets by the facile and environment-friendly methods. The multifunctional f-F-Ce nanosheets are incorporated into the Pebax (Pebax 1657) matrix to fabricate mixed matrix membranes (MMMs) for efficient CO2 separation. The f-F-Ce nanosheets play versatile parts in