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observed; the distance between the nitrogen atom and terminal carbon of the alkyl chain in cation decreases with increasing the pressure. When the Li-ion is present in the mixture, the cis configuration of anions slightly dominates the trans configuration. The conformational change of anions from trans to cis occurs when pressure changes from a low to a high value.AuIII-oxygen adducts have been implicated as intermediates in homogeneous and heterogeneous Au oxidation catalysis, but their reactivity is under-explored. Complex 1, ([AuIII(O