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A strategy is proposed for the design of wall envelopes to improve unsteady thermal performance in non-air-conditioned buildings and to reduce energy costs in air-conditioned buildings. The thermophysical properties of building materials (e.g., burnt bricks, mud bricks, laterite stone, cinder concrete, and expanded polystyrene) were measured experimentally using a thermal analyzer. A total of 28 combinations for composite walls were designed with expanded polystyrene as an insulation material based on seven criteria and were subjected