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Membrane capacitive deionization (MCDI) is a prospective desalination technology that removes ions using an electric potential difference across charged porous carbon electrodes. Natural organic matter (NOM) in feed water could influence the electrochemical process by leading to pore-blockages or forming a cake layer on the ion-exchange membrane-coated porous carbon electrode, thereby hindering ion removal. In this study, we explored the influence of different types of NOM, namely, humic acid (HA) and tannic acid (TA), on the MCDI desalin