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This review summarizes the progress in open tubular ion chromatography (OTIC) over the period from 1981 to 2020. Although OTIC columns provide superior column efficiency, require very little sample volumes, and consume a minimum level of eluents compared to regular packed columns, not many reports can be found from the literature mainly due to the difficulties in the preparation of OTIC columns and the harsh system requirements, such as pL-nL injections and extremely small detection volumes. However, technical advances, e.g., capacitively
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