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The purpose of the present work was, therefore, to assess the influence of nitrogen substituents on the stability (ΔΕs-t), band gaps (ΔΕHOMO-LUMO), N, ω, and heat of hydrogenation (ΔEH). This investigation is aimed to introduce novel germylenes that can be applied as cumulated multi-dentate NHG̈e ligands. Due to the variation in shape and curvature of the clavicle, plates often have to be adjusted during surgery to acquire a good fit. Poorly fitted plates can cause discomfort, eventually requiring implant removal. 3D-printed replicas of