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In this paper, the gas pollutants in motor vehicle exhaust are taken as the research object. The diagnostic index system of motor vehicle gas pollutants on environmental pollution is constructed, based on the environmental pollution caused by motor vehicle exhaust. The emission intensity of various types of vehicles was studied. The least-square method is used to construct the diagnostic functions of different types of vehicle gas pollutants; the vehicle emission factors of different types of motor vehicle gas pollutants are obtained. By