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The admixture of Ir 5d orbitals in the spin-majority channel are mainly responsible for conductivity, while the spin minority channel remains an insulator. Surprisingly, a substantial reduction and enhancement of spin moment are found on non-equivalent Ir and oxygen ions, respectively. This leads the Ir ion in a mixed-valence state of [Formula see text] and [Formula see text] in all doped systems having configurations of [Formula see text] ([Formula see text]) and [Formula see text] ([Formula see text]), respectively. Hence, the present