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As a result, it is revealed that the relationship of Δex with the quasi-particle gap deviates largely from the linear one previously reported for graphene and many other two-dimensional materials.Based on density functional theory, the electronic structure and magnetic properties of monolayer PtSe2 doped with different atoms were studied. The Pt and Se atoms are replaced by a transition metal atom (Mn) and a non-metal atom X (X = N, P, As), respectively. The pristine monolayer PtSe2 is a semiconductor with an indirect band gap of 1.352 e