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The performed X-ray adsorption spectra (XAS) provides evidence that Ir 5d orbital degeneracy is eliminated because of multiple orbitals being semi-occupied in the presence of Fe, which is mainly responsible for the enhancement of OER activity. These findings open an opportunity for the design and preparation of more efficient OER catalysts of transition metal oxides by utilization of the MOF materials. It should be highlighted that a long-term stability of this catalyst run at a high current density in acidic conditions still faces great