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To the best of our knowledge, this is the first time that a Cd-based MOF and MMMs have been applied as a catalyst for the production of a β-amino acid. The combination of catalytic MOF and PVDF provides a way to simplify the design of a flow reactor and reduce the costs of manufacturing.Water is ubiquitous on Earth and dominates chemical and biological processes in daily life. However, how water behaves under some critical conditions is not fully understood. In this paper, we employed quantum first-principles calculations and dynamics s