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Right here, through experimental and simulation studies, we demonstrate the part of co-ions as a function of co-ion size on the relationship because of the macroions (using and as designs) as well as the relevant self-assembly into blackberry-type structures in dilute solutions. Several regimes of unique co-ion effects tend to be demonstrably identified little ions (halides, oxoacid ions), subnanometer-scaled cumbersome ions (lacunary Keggin and do