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Iron-assisted biological wastewater treatment processes have shown a promising potential in removing various types of contaminants. Synergistic effects between iron and microbes on the contaminant degradation make the role of iron beyond that of a nutritional necessity. Exploration of the synergistic mechanisms and the interactions between iron species and microbes and their metabolic products in bio‑iron systems is therefore of significant importance. Iron, including zero-valent iron, ferrous/ferric ions and iron minerals are all report
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