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Fine particulate matter (PM) air pollution has increasingly become a global problem; thus, high-performance air filtration materials are in great demand. Herein, we first prepared a biodegradable hierarchically structured nanocellulose-implanted air filter with a high filtration capacity using a freeze-drying technique. In this hierarchically structured air filter, porous structures of corrugated paper and cellulose nanofibrils (CNFs) were used as a frame and functional fillers, respectively. The self-assembled structure of the CNF fille