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Commercial sodium citrate is proposed as the self-sacrificial cathode additive for the first time to offset the initial sodium loss. The optimum additive can obviously increase the energy density of the as-constructed hard carbon//Na3V2(PO4)2F3/rGO full-cell by 28.9% without sacrificing its other electrochemical properties, showing promising application prospects in sodium ion batteries.In this work, by using N-methoxybenzamides as efficient acyl nitrene precursors, an iron-catalyzed formal cis-haloamidation of alkyne is reported. Withou
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