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icropollutant removal by UV/chlorine oxidation under real water matrix.Sulfate radical (SO4•-) based oxidation shows great promise in wastewater treatment and subsurface remediation. For the first time, we demonstrated that SO4•- could induce the transformation of ammonium (NH4+) to nitrophenolic byproducts. Using high-resolution mass spectrometry in combination with 15N labeling, mono-nitro and di-nitro phenolic byproducts were identified in a sample containing 1 mM NH4+ and 10 mg/L natural organic matter (NOM) following heat activated pe