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621-2.53 μg PM2.5 /cm2. This method can be re-applied in different regions and the PM concentration on skin can inform future studies on the health impact of air pollution on skin.We report a visible light-responsive bilayer actuator driven by the photothermal properties of a unique molecular photoswitch donor-acceptor Stenhouse adduct (DASA). We demonstrate a synthetic platform to chemically conjugate DASA to a load-bearing poly(hexyl methacrylate) (PHMA) matrix via Diels-Alder click chemistry that enables access to stimuli-responsive