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Here, we have described the design, preparation and detailed characterization of a new acetoxy functionalized aluminium based metal-organic framework (MOF) called CAU-10-OCOCH3 (1) (CAU stands for Christian-Albrechts-University). The desolvated compound was employed for the detection of perborate in a pure aqueous environment. The presented MOF based perborate sensing probe (1) was synthesized by employing 5-acetoxyisophthalic acid and AlCl3·6H2O as the linker molecule and metal salt source, respectively, in DMF/H2O medium at 120 °C for