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Spatial confinement is a desirable successful strategy to trap sulfur within its porous host and has been widely applied in lithium-sulfur (Li-S) batteries. However, physical confinement alone is currently not enough to reduce the lithium polysulfide (Li2Sn, 4 ≤ n ≤ 8, LIPSs) shuttle effect with sluggish LIPS-dissolving kinetics. In this work, we have integrated spatial confinement with a polar catalyst, and designed a three-dimensional (3D) interconnected, Co decorated and N doped porous carbon nanofiber (Co/N-PCNF) network. This Co/N-PCNF
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