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Real time photo-rheology experiments demonstrated the outstanding efficiency associated with PAMAM BAPOs as photoinitiators for free radical polymerization. Extremely, it's unearthed that PAMAM BAPOs also behave as crosslinking agents to convert monofunctional methacrylate monomers into thermosetting sites without the further additives. According to the number of the connected BAPOs, thermosets with a different level of crosslinking and inflammation capacity in liquid h