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The microbial nutrient recovery cell i.e. modified microbial fuel cell containing a middle recovery chamber can be used to purify wastewater and remove valuable nutrients, while simultaneously generating electricity. The study investigated nutrient removal and microorganism interactions with carbon (CB- HT and CB- APTES) and stainless steel (SSB-HT) modified anodes used in microbial nutrient recovery cells. The removal efficiencies of ammonium ions were found higher in carbon-based CB-APTES (~98%) and CB-HT (~98.27%) systems in compari