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6% (open-circuit voltage 775.6 mV, short-circuit current 15.5 mA/cm2, fill factor 54.9%, area 0.2 cm2) was obtained when the Na2Se thickness was 20 nm.The world is confronted with the depletion of natural resources due to their unsustainable use and the increasing size of populations. In this context, the efficient use of by-products, residues and wastes generated from agro-industrial and food processing opens the perspective for a wide range of benefits. In particular, legume residues are produced yearly in very large amounts and may