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The α-carbonyl carbene is checked making use of a band with solvent-dependent wavenumber when you look at the range 1627-1645 cm-1. A computed two-dimensional slice associated with potential power area when it comes to result of the singlet α-carbonyl carbene with methanol suggests that the enol types without a barrier and that this response is promoted by an intermolecular hydrogen relationship from methanol to your carbonyl oxygen