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The ability of the T and Z atoms of TR3ZR2 to engage in a noncovalent interaction with NH3 is assessed by DFT calculations, where the T atom refers to C, Si, and Ge; Z = As, Sb, and P; and substituents R = H and F. In most instances, the tetrel bond (T is both stronger and shorter than the pnicogen bond (Z. These two bond strengths can be equalized, or preference shifted to the ZB, if F substituents are placed on the Z and H on the T atoms. Employing C as the T atom results in a very weak TB, with the ZB clearly favored energetically
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