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The photophysical properties of donor (D)-acceptor (A) polymers were studied by designing two types of polymers, (D-σ-A) n and (D-π-A) n , with non-conjugated alkyl (sp3) and π-conjugated (sp2) linkers using π-extended donor and acceptor monomers that exhibit planar A-D-A structures. The non-conjugated alkyl linker provides structural flexibility to the (D-σ-A) n polymers, while the π-conjugated linker retains the rigid structure of the (D-π-A) n polymers. Photoinduced energy transfer occurs from the large donor to acceptor units in bot
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