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Synthesis of optically active gem-difluorinated organic molecules attracts a great deal of interest due to their unique properties in pharmaceutical and agrochemical areas. Herein, a series of enantioenriched α,α-difluoro-β-arylbutanoic esters were prepared in high yields (83-99%) with moderate to excellent enantioselectivities (≤973 er) by palladium-catalyzed asymmetric hydrogenation.Nanoscale superlattices represent a compelling platform for designed materials as the specific identity and spatial arrangement of constituent layers can