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Our results further indicate that previously banned long-chain PFAAs had persistent residuals in this coastal marine ecosystem, and that emerging short-chain PFAAs had high concentrations in some species but showed no biomagnification.Carbon-catalyzed persulfate activation for the removal of gaseous volatile organic compounds (VOCs) has not been reported yet, and the corresponding fundamental mechanisms of VOCs adsorption and the subsequent VOCs degradation remain controversial. In this work, theoretical chemistry calcu