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Evaluating entropy rate of high-dimensional chaos and shot noise from analog raw signals remains elusive and important in information security. We experimentally present an accurate assessment of entropy rate for physical process randomness. The entropy generation of optical-feedback laser chaos and physical randomness limit from shot noise are quantified and unambiguously discriminated using the growth rate of average permutation entropy value in memory time. The permutation entropy difference of filtered laser chaos with varying embeddi

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