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© 2020 The Authors. Cancer Medicine published by John Wiley Sons Ltd.Phenol-based macrocyclic arenes have been widely used in supramolecular chemistry, significantly enriching the toolbox of the field. In contrast, naphthol-based macrocyclic arenes are rather underdeveloped. Very recently, Gaeta and co-workers successfully synthesized such macrocycles (referred to as prism[n]arenes) with good guest-binding ability by reacting 2,6-dimethoxynaphthalene with paraformaldehyde under optimized conditions. In view of the simple synthesis
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